Continuous-time approximation of Stochastic Gradient Descent (SGD) is a crucial tool to study its escaping behaviors from stationary points. However, existing stochastic differential equation (SDE) models fail to fully capture these behaviors, even for simple quadratic objectives. Built on a novel stochastic backward error analysis framework, we derive the Hessian-Aware Stochastic Modified Equation (HA-SME), an SDE that incorporates Hessian information of the objective function into both its drift and diffusion terms. Our analysis shows that HA-SME matches the order-best approximation error guarantee among existing SDE models in the literature, while achieving a significantly reduced dependence on the smoothness parameter of the objective. Further, for quadratic objectives, under mild conditions, HA-SME is proved to be the first SDE model that recovers exactly the SGD dynamics in the distributional sense. Consequently, when the local landscape near a stationary point can be approximated by quadratics, HA-SME is expected to accurately predict the local escaping behaviors of SGD.