Duality is a pervasive and important principle in mathematics. Not only has it fascinated researchers in many different fields but it has also been used extensively in optimization, statistics, and machine-learning (ML), giving rise to powerful tools such as Fenchel duality in convex optimization, representer theorems in kernel methods and Bayesian nonparametrics, and dually-flat spaces in information geometry. Such applications have played an important role in the past, but lately we do not see much work on duality principles, especially in deep learning. For example, Lagrange duality can be useful for model explanation because it allows us to measure sensitivity of certain perturbations, but this is not yet fully exploited. This slowdown is perhaps due to a growing focus on nonconvex and nonlinear problems where duality does not seem to be directly applicable. There have not been any workshops on duality in recent years. With this workshop, we aim to revive the interest of the ML community in duality principles.The goal of the workshop is to bring together researchers working on various duality concepts from many different fields, and discuss new applications for modern machine learning, especially focusing on topics such as model understanding, explanation, and adaptation in deep learning and reinforcement learning. Our organizers, speakers, and panelists have expertise working on such topics and form a diverse group in terms of backgrounds, fields, race, gender, and country. We also have an advisory committee who have been helping us in organization and communication. Overall, we aim to cover a wide-range of topics from both theory and application of duality.